It's not a question of xtalk when you split one input. It would only be an issue if you sent the head to one input and the rim to a different input. What you're proposing will work fine. Before I got my second module, I had several Y adapters on one module without any xtalk issues. Just remember, you can only use zone xtalk if you have xtalk between the two pads on the same trigger input.
As stated above, you cannot trigger both at the same time. The module prevents that from happening. Kind of funny... they give you zone xtalk, but the module prevents it... I guess so you don't get the mute group effect where striking the second trigger mutes the strike of the first trigger (Hellfire's additional method of additional cymbal chokes!!!) Although, I don't think this is 100% true for all inputs (think ride, where you can get the bow and bell sound at the same time... not to mention the crash sound which is a function of two triggers at the same time).
You can also add additional chokable cymbals using a Y on the same input. The limitation here is that you're stuck with the same kit settings, sounds and all, for both. Not really a big deal as most larger sets usually have pairings of a few cymbals on different sides of the kit.